Calculate the pH of each of the following solutions (Ka and Kb values are given in Appendix D): (b) 0.100 M hydrogen chromate ion 1HCrO4-2
Ch.16 - Acid-Base Equilibria
Chapter 16, Problem 62
The active ingredient in aspirin is acetylsalicylic acid 1HC9H7O42, a monoprotic acid with Ka = 3.3 * 10^-4 at 25 °C. What is the pH of a solution obtained by dissolving two extra-strength aspirin tablets, each containing 500 mg of acetylsalicylic acid, in 250 mL of water?
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Calculate the total mass of acetylsalicylic acid by multiplying the mass of one tablet by the number of tablets.
Convert the total mass of acetylsalicylic acid to moles using its molar mass (180.16 g/mol).
Determine the concentration of acetylsalicylic acid in the solution by dividing the number of moles by the volume of the solution in liters.
Set up the expression for the acid dissociation constant (Ka) for acetylsalicylic acid: \( Ka = \frac{[H^+][A^-]}{[HA]} \), where [HA] is the initial concentration of the acid, and [H^+] and [A^-] are the concentrations of the hydrogen ion and the acetate ion at equilibrium.
Assume that the initial concentration of [H^+] and [A^-] is negligible, and solve for [H^+] using the approximation \( [H^+] = \sqrt{Ka \times [HA]} \), then calculate the pH using \( pH = -\log[H^+] \).
Related Practice
Textbook Question
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Textbook Question
Determine the pH of each of the following solutions (Ka and Kb values are given in Appendix D): (c) 0.165 M hydroxylamine.
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Open Question
Saccharin, a sugar substitute, is a weak acid with pKa = 2.32 at 25 °C. It ionizes in aqueous solution as follows: HNC7H4SO31(aq) ⇌ H+(aq) + NC7H4SO3-(aq). What is the pH of a 0.10 M solution of this substance?
Open Question
Calculate the percent ionization of hydrazoic acid (HN3) in solutions of each of the following concentrations (Ka is given in Appendix D): (a) 0.400 M, (b) 0.100 M, (c) 0.0400 M.
Textbook Question
Calculate the percent ionization of propionic acid 1C2H5COOH2 in solutions of each of the following concentrations 1Ka is given in Appendix D): (a) 0.250 M
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Textbook Question
Citric acid, which is present in citrus fruits, is a triprotic acid (Table 16.3). (a) Calculate the pH of a 0.040 M solution of citric acid. (b) Did you have to make any approximations or assumptions in completing your calculations? (c) Is the concentration of citrate ion 1C6H5O7 3-2 equal to, less than, or greater than the H+ ion concentration?
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