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Ch.16 - Acid-Base Equilibria
Chapter 16, Problem 93

Ammonia, NH3, acts as an Arrhenius base, a Brønsted-Lowry base, and a Lewis base, in aqueous solution. Write out the reaction NH3 undergoes with water and explain what properties of ammonia correspond to each of the three definitions of “base.”

Verified step by step guidance
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Step 1: Write the chemical equation for the reaction of ammonia (NH3) with water (H2O). Ammonia accepts a proton (H+) from water, forming ammonium ion (NH4+) and hydroxide ion (OH-). The equation is: NH3 + H2O ⇌ NH4+ + OH-.
Step 2: Explain the Arrhenius base definition. An Arrhenius base is a substance that increases the concentration of hydroxide ions (OH-) in aqueous solution. In this reaction, NH3 increases the OH- concentration, thus acting as an Arrhenius base.
Step 3: Explain the Brønsted-Lowry base definition. A Brønsted-Lowry base is a substance that can accept a proton (H+). In this reaction, NH3 accepts a proton from H2O to form NH4+, demonstrating its role as a Brønsted-Lowry base.
Step 4: Explain the Lewis base definition. A Lewis base is a substance that can donate an electron pair. NH3 has a lone pair of electrons on the nitrogen atom, which it can donate to form a bond with a proton (H+), thus acting as a Lewis base.
Step 5: Summarize the properties of NH3 in the context of these definitions. NH3 acts as an Arrhenius base by increasing OH- concentration, as a Brønsted-Lowry base by accepting a proton, and as a Lewis base by donating an electron pair.
Related Practice
Textbook Question

Based on their compositions and structures and on conjugate acid–base relationships, select the stronger base in each of the following pairs: (b) PO43- or AsO43-

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Textbook Question

Indicate whether each of the following statements is true or false. For each statement that is false, correct the statement to make it true. (a) In general, the acidity of binary acids increases from left to right in a given row of the periodic table. (b) In a series of acids that have the same central atom, acid strength increases with the number of hydrogen atoms bonded to the central atom. (c) Hydrotelluric acid 1H2Te2 is a stronger acid than H2S because Te is more electronegative than S.

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Textbook Question

Indicate whether each of the following statements is true or false. For each statement that is false, correct the statement to make it true. (a) Acid strength in a series of H¬A molecules increases with increasing size of A. (b) For acids of the same general structure but differing electronegativities of the central atoms, acid strength decreases with increasing electronegativity of the central atom. (c) The strongest acid known is HF because fluorine is the most electronegative element.

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Textbook Question
The fluoride ion reacts with water to produce HF. (c) Is fluoride acting as a Lewis acid or as a Lewis base when reacting with water?
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Textbook Question

Identify the Lewis acid and Lewis base among the reactants in each of the following reactions: (d) HIO1lq2 + NH2-1lq2 Δ NH31lq2 + IO-1lq2(lq denotes liquid ammonia as solvent)

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Textbook Question

Identify the Lewis acid and Lewis base in each of the following reactions: (b) FeBr31s2 + Br-1aq2 Δ FeBr4-1aq2

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