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Ch.12 - Solids and Modern Materials
Chapter 12, Problem 74

If you want to dope GaAs to make a p-type semiconductor with an element to replace As, which element(s) would you pick?

Verified step by step guidance
1
Identify the position of GaAs in the periodic table. Gallium (Ga) is in group 13 and arsenic (As) is in group 15.
Understand that a p-type semiconductor is created by introducing an element with fewer valence electrons than the element it replaces, creating 'holes' or positive charge carriers.
Since arsenic (As) is in group 15, it has 5 valence electrons. To create a p-type semiconductor, choose an element from group 14, which has 4 valence electrons.
Consider elements in group 14 that can replace arsenic in the GaAs lattice. These elements include carbon (C), silicon (Si), germanium (Ge), tin (Sn), and lead (Pb).
Select an appropriate group 14 element based on factors such as atomic size and compatibility with the GaAs lattice structure, with silicon (Si) and germanium (Ge) being common choices.