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MO Theory: Heteronuclear Diatomic Molecules
12. Molecular Shapes & Valence Bond Theory / MO Theory: Heteronuclear Diatomic Molecules / Problem 1

The structure of cyclobutadienyl dianion, C4H42−, is shown below. It can be described by the following energy diagrams of its π molecular orbitals when only the π bonds and not the σ bonds are taken into account: 

Energy diagram for cyclobutadienyl dianion's pi molecular orbitals.

Diagram showing the arrangement of 4 p orbitals and energy levels for cyclobutadienyl anion.

Assign the proper numbers of π electrons to the various molecular orbitals to complete the MO energy diagram. Use up/down arrows to indicate the electrons.

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