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Hess's Law
8. Thermochemistry / Hess's Law / Problem 3

Select the correct addition of (i) and (ii) to get (iii)
(i) POCl3 + ClPCl5 + 1/2 O2 
(ii) PCl3 + Cl2 → PCl5
(iii) 2 POCl3 → 2 PCl3 + O2


a.
POCl3 + Cl2  → PCl5 + 1/2 O2
PCl3 + 1/2 O→ POCl3 ________________________
PCl3 + Cl→ PCl


b.
POCl3 + Cl2  → PCl5 + 1/2 O2

PCl→ PCl3 + Cl2________________________
POCl3 → PCl3 + 1/2 O2


c.
2 [ POCl3 + Cl2  → PCl5 + O]

2 [ PCl3 + O→ 2 POCl3 ]________________________
2 POCl3 → 2 PCl3 + O2


d.  
2 [ POCl3 + Cl2  → PCl5 + 1/2 O]

2 [ PCl→ PCl3 + Cl]________________________
2 POCl3 → 2 PCl3 + O2

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