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A 2.00 L vessel is charged with 46.0 g of N2O4 and then heated to 350 K. Calculate the equilibrium molar concentrations of N2O4 and NO2. Use the assumption that ΔHº and ΔSº do not vary with temperature and recall that ΔGº is related with the pressure equilibrium constant.
For the reaction 2 HgO(s) → 2 Hg(l) + O2(g), use the given thermodynamic data to calculate the equilibrium pressure of O2 in a 1.5 L vessel that contains 10 g of HgO at 350 ºC. Use the assumption that ΔHº and ΔSº do not vary with temperature.
Given the following data
What are the ΔH°, ΔG°, K, and ΔS ° for the reaction Sn (s) + 2 Cl2 (g) → SnCl4 (g) at 25 °C?
Consider the gaseous equilibrium for the dimerization of NO2 at 350 K.
2 NO2(g) ⇌ N2O4(g)
What is the value of ΔG when NO2 = 1.23 atm and N2O4 = 2.45 atm? Use the following ΔG° values:
ΔG° (NO2(g)) = 51.3 kJ/mol
ΔG° (N2O4(g)) = 99.8 kJ/mol
In which direction (forward or reverse) this reaction is spontaneous under the given conditions?
Molecular iodine sublimes at 184 ºC. The standard molar entropies for solid and gaseous iodine are S°I2(s) = 116.1 J/mol K and S°I2(g) = 260.7 J/mol K. Determine the temperature where iodine exhibits a vapor pressure of 430 mmHg.
Given the following decomposition reaction:
P4(g) → 2 P2(g); ΔH°rxn = 229.1 kJ
Calculate the percentage of 0.100 atm P4 that decomposes at 314 K if 47.00% of P4 decomposes to P2 when equilibrium at 298 K is reached.
Based on the given equilibrium constant at different temperatures, what are ΔS°rxn and ΔH°rxn for the reaction?
2 SO2 (g) + O2 → 2 SO3 (g)