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Entropy Calculations - Part 2 of 2
19. Chemical Thermodynamics / Entropy Calculations / Problem 6

Ethanol can be prepared in several ways. It can be produced during alcohol fermentation (Reaction A). It is also produced commercially from ethylene (Reaction B). Calculate the ΔG°rxn (kJ•mol–1) of each reaction.

A. C6H12O6(s) → 2 C2H5OH(l) + 2 CO2(g)

B. C2H4(g) + H2O(g) → C2H5OH(l)

Determine which method requires less energy under standard conditions.

Substance            ΔG°f (kJ/mol)
C6H12O6(s)           –910.4
C2H4(g)                   68.4
C2H5OH(l)           –174.8
H2O(g)                 –228.6
CO2(g)                 –394.4

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