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Constant-Volume Calorimetry
Constant-Volume Calorimetry
8. Thermochemistry / Constant-Volume Calorimetry / Problem 2

When 0.531 g sample of toluene (C7H8) was combusted in a bomb calorimeter the temperature rises 2.635 °C and when 0.425 g sample of phenol (C6H6O) was combusted in a bomb calorimeter the temperature rises 1.613 °C. Using the value 42.48 kJ/g for the heat of combustion of toluene, the heat of combustion per mole of phenol was calculated to be 3058 kJ/mol.

Calculate the uncertainty in the calculated value of the molar heat of combustion of phenol if there is an uncertainty of 0.001 °C in each temperature reading and 0.001 g for the mass of the samples.

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