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Classify the following processes as spontaneous or nonspontaneous:
A. An icicle melting on your hand on a cold day
B. Conversion of water into steam at 120 °C
C. A stone rolling uphill
D. Dissolution of salt in water
Identify which of the processes below are non-spontaneous and state if the non-spontaneous processes are impossible.
i. water falling from waterfalls
ii. riding a skateboard uphill
iii. boiling of water
iv. turning graphite into diamond
Consider a system with 3.62 mole of Acetone (C3H6O). Calculate the change in entropy that occurs in the system when it condenses at its boiling point of 56.1 °C and the heat of vaporization is 29.1 kJ/mol
Given the following data:
Calculate ΔSfus and ΔSvap for K.
ΔSfus = _________ J•K–1•mol–1
ΔSvap = _________ J•K–1•mol–1
If the state of the system consisting of three standard playing dice is determined by the sum of the values displayed on the top faces of the three dice, what is the system's absolute entropy?
What happens to the number of microstates when the volume of the system decreases?
What are the signs of the change of entropy for each of the given processes below?
(a) Fe3+ and OH– ions forming solid Fe(OH)3.
(b) Methane gas is released from solid wastes.
(c) A gas condenses.
(d) A liquid evaporates.
Arrange the following substances in order of increasing (least to most) molar entropy at 298 K.
Al(s) CO2(g) Ne(g)
Rank each set of substances in order of increasing standard molar entropy (S°). Explain your reasoning. NH3(g); Ar(g); SeO2(g); CH3CH2CH2OH(g); Kr(g)
Using the thermodynamic data below calculate the ΔS°rxn for the following reaction and justify the change in entropy.
2 NaF(s) + Cl2(g) → 2 NaCl(s) + F2(g)
The decomposition of silicon dioxide produces solid silicon and oxygen gas.
What is the ΔSsys, ΔSsurr, and ΔStotal for the reaction? At 25 °C, under standard-state conditions, what is the spontaneity of the reaction?