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Cyclobutane gas decomposes to butene gas when heated.
The equilibrium constant Kc for this reaction is 3.0×104 at 700 K. What is the value of Kp at 700 K?
Calculate Kc for each reaction. b. CH4(g) + H2O(g) ⇌ CO(g) + 3 H2(g), Kp = 2.5 x 103 (at 1200 K)
At 298 K, the Kc for the reaction 2 H2S(g) ⇋ 2 H2(g) + S2(g) is 1.67×10−7. What is the Kc for the reaction H2S(g) ⇋ H2(g) + 1/2 S2(g) at the same temperature?
The reaction 2 SO3(g) + N2(g) ⇌ 2 NO3(g) + S2(g) has Kp of 4.5 x 10-7 at 1000 K. What is the Kp of the reaction below at the same temperature?
2 NO3(g) + S2(g) ⇌ 2 SO3(g) + N2(g)
Consider the following equilibrium reaction: 2 NOBr(g) + Cl2(g) ⇌ 2 NO(g) + 2 BrCl(g), ΔH° = +47.4 kJ.
(a) How will the concentration of NO change when the temperature of the system is lowered?
(b) How will the equilibrium constant (Kc) change when the temperature of the system is increased?
Explain your answer using Le Chatelier's principle.
The reaction N2(g) + 3 H2(g) ⇌ 2 NH3(g) has the following values at 298 K: Kp = 6.2×105 and ΔH° = –92.2 kJ. Consider the following changes below which will result in an increase in the partial pressure of NH3 at equilibrium. Which of the changes will result in the highest increase in the partial pressure of NH3? Justify your answer.
I. Adding 0.20 mol of N2
III. Adding 0.20 mol of H2
III. Lowering the temperature to 250 K
A. Adding 0.20 mol of N2 will result in the highest increase in partial pressure of NH3 because it will produce a greater amount of NH3.
B. Adding 0.20 mol of H2 will result in the highest increase in partial pressure of NH3 because it is the limiting reactant.
C. Lowering the temperature to 250 K will result in the highest increase in partial pressure of NH3 because it will shift the equilibrium reaction to the right.
D. All of the above will result in the same increase in the partial pressure of NH3.
Determine the condition that will increase the amount of C4H8Br2 at equilibrium for the endothermic reaction:
C4H8 (g) + Cl2 (g) ⇌ C4H8Br2 (g)
a. removing Cl2 from the mixture
b. increasing the volume of the reaction
c. increasing the amount of C4H8
d. increasing the temperature of the reaction
A reaction chamber initially contains a mixture of NO(g) and Cl2(g) at 1069 K, with pressures of 4.564 atm and 2.801 atm, respectively. The following reaction occurs: 2 NO(g) + Cl2(g) ⇌ 2 NOCl(g). Calculate the value of Kc if the total pressure at equilibrium is 5.45 atm.
Consider the following reaction 375°C: SO2(g) + Cl2(g) ⇌ SO2Cl2(g), Kc = 25.9.
In a reaction vessel, 2.50 M of SO2(g) and 2.25 M of Cl2(g) were mixed. Calculate the concentration of all species once equilibrium is reached at 375°C.
The reaction of hydrogen (H2) and iodine (I2) produces hydrogen iodide (HI) according to the following equation:
H2(g) + I2(s) ⇌ 2 HI(g)
An equilibrium mixture contains the following concentrations/amounts of the reactants and products in a 1.00 L container: H2 = 0.234 mol, HI = 0.348 mol and I2 = 10.0 g.
If an additional 0.0700 moles of H2 are added to the reaction mixture, how many moles of HI are produced when the equilibrium is reestablished?
Consider the following reaction 2 LM ⇌ L2 + M2 with an equilibrium constant of Kc = 0.25 The diagram below shows a mixture of the molecules L2 (yellow), M2 (black), and LM. Determine the correct statement about the mixture.
The following reaction has an equilibrium constant of 0.953 at 125 °C.
N2H4 (g) → N2 (g) + 2 H2 (g)
At 125 °C, 3.00x10-3 M N2H4, 4.50x10-5 M N2, 3.50x10-5 M H2 were mixed in a flask. Will the mixture reach equilibrium? If not, in which direction should the reaction proceed to reach equilibrium?
A sealed container with the gases at equilibrium at 298 K contains PN2O4 = 0.512 atm and PN2O = 0.0607 atm. A second container, under the same temperature, contains PN2O4 = 0.163 atm and PN2O = 0.0342 atm. The gases follow the reaction: N2O4(g) ⇌ 2 N2O(g). Identify if the second reaction is at equilibrium. If it is not in equilibrium, calculate the equilibrium partial pressure of N2O.