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Ch.9 - Chemical Bonding I: The Lewis Model
Chapter 9, Problem 101

Draw the Lewis structure for HCSNH2. The carbon and nitrogen atoms are bonded together, and the sulfur atom is bonded to the carbon atom. Label each bond in the molecule as polar or nonpolar.

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<Identify the total number of valence electrons in the molecule. Hydrogen (H) has 1 valence electron, carbon (C) has 4, sulfur (S) has 6, and nitrogen (N) has 5. Calculate the total by adding these together.>
<Arrange the atoms in the specified order: H-C-S-N-H-H. Connect the atoms with single bonds initially, ensuring that C is bonded to S and N, and N is bonded to the two H atoms.>
<Distribute the remaining valence electrons to satisfy the octet rule for each atom, starting with the most electronegative atoms (S and N). Remember that hydrogen only needs 2 electrons.>
<Check the formal charges on each atom to ensure the most stable structure. Adjust the bonding if necessary to minimize formal charges, possibly by forming double bonds.>
<Determine the polarity of each bond by comparing the electronegativity of the bonded atoms. A bond is polar if there is a significant difference in electronegativity between the two atoms. Label each bond as polar or nonpolar based on this analysis.>