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Ch.18 - Free Energy and Thermodynamics
Chapter 18, Problem 66

Consider the reaction: CaCO3(s) → CaO(s) + CO2(g). Estimate ΔG° for this reaction at each temperature and predict whether or not the reaction is spontaneous. (Assume that ΔH° and ΔS° do not change too much within the given temperature range.) a. 298 K b. 1055 K c. 1455 K.

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1
Identify the given reaction: \( \text{CaCO}_3(s) \rightarrow \text{CaO}(s) + \text{CO}_2(g) \). This is a decomposition reaction.
Recall the Gibbs free energy equation: \( \Delta G^\circ = \Delta H^\circ - T\Delta S^\circ \).
Determine the standard enthalpy change (\( \Delta H^\circ \)) and the standard entropy change (\( \Delta S^\circ \)) for the reaction from standard tables.
For each temperature (298 K, 1055 K, 1455 K), substitute the values of \( \Delta H^\circ \), \( \Delta S^\circ \), and the given temperature \( T \) into the Gibbs free energy equation to calculate \( \Delta G^\circ \).
Analyze the sign of \( \Delta G^\circ \) for each temperature: if \( \Delta G^\circ < 0 \), the reaction is spontaneous; if \( \Delta G^\circ > 0 \), the reaction is non-spontaneous.
Related Practice
Open Question
Using standard free energies of formation, calculate ΔG° at 25 °C for each reaction in Problem 62. How do the values of ΔG° calculated this way compare to those calculated from ΔH° and ΔS°? Which of the two methods can determine how ΔG° changes with temperature?
Open Question
Is the question formulated correctly? If not, please correct it. Here is the question: 'Consider the reaction: 2 NO( g) + O2( g) → 2 NO2( g). Estimate ΔG° for this reaction at each temperature and predict whether or not the reaction is spontaneous, assuming that ΔH° and ΔS° do not change significantly within the given temperature range. a. 298 K b. 855 K.'
Textbook Question

Consider the reaction: 2 NO(g) + O2(g) → 2 NO2(g) Estimate ΔG° for this reaction at each temperature and predict whether or not the reaction is spontaneous. (Assume that ΔH° and ΔS° do not change too much within the given temperature range.) b. 715 K

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Textbook Question

Determine ΔG° for the reaction: Fe2O3(s) + 3 CO(g) → 2 Fe(s) + 3 CO2(g) Use the following reactions with known ΔG°rxn values:

2 Fe(s) + 3/2 O2(g) → Fe2O3(s) ΔG°rxn = -742.2 kJ

CO(g) + 12 O2( g) → CO2(g) ΔG°rxn = -257.2 kJ

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Open Question
Calculate ΔG°rxn for the reaction: CaCO3(s) → CaO(s) + CO2(g). Use the following reactions and given ΔG°rxn values: Ca(s) + CO2(g) + 1/2 O2(g) → CaCO3(s) ΔG°rxn = -734.4 kJ, 2 Ca(s) + O2(g) → 2 CaO(s) ΔG°rxn = -1206.6 kJ.
Open Question
Consider the sublimation of iodine at 25.0 °C: I2(s) → I2(g). a. Find ΔG°rxn at 25.0 °C.