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Ch.17 - Additional Aspects of Aqueous Equilibria

Chapter 17, Problem 88b

Two buffers are prepared by adding an equal number of moles of formic acid (HCOOH) and sodium formate (HCOONa) to enough water to make 1.00 L of solution. Buffer A is prepared using 1.00 mol each of formic acid and sodium formate. Buffer B is prepared by using 0.010 mol of each. (b) Which buffer will have the greater buffer capacity?

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Hello everyone. So in this video we're trying to see if buffer X. Or buffer Y. Has a higher buffering capacity. So in our buffer we have our H. C. I. O. And R C L. O minus. And of course that C L O minus is going to be our conjugate base. So we're adding our asset to our conjugate base. And it creates this reaction which is of H 30. Plus to the conjugate base to go ahead and give us Hc I. O. As well as H 20. And if we're adding base too weak acid then we will get O. H minus plus H. C. I. O. To go ahead and create C. L. O minus and water. So they graded the absolute concentration of our weak acid and a contributor base. Then let's write that we can say that that is a case the more weak acid or contradict base which I'll just simplify to CB that can react and neutralize are added either our acid or base. And that's how we can see if it has a higher or high buffering capacity just to see which is a better buffer essentially. So because of this we can look at our reactions that we just wrote we can determine that the buffer X will have a higher buffering capacity because again the higher or greater the absolute concentration of weak acid and conjugate base, the more weak acid or contra bass, bass that can react and neutralize that acid or base that we're going to go ahead and add. So this right here is going to be my final answer for this problem. Thank you all so much for watching.
Related Practice
Textbook Question

Derive an equation similar to the Henderson–Hasselbalch equation relating the pOH of a buffer to the pKb of its base component.

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Textbook Question

Rainwater is acidic because CO21g2 dissolves in the water, creating carbonic acid, H2CO3. If the rainwater is too acidic, it will react with limestone and seashells (which are principally made of calcium carbonate, CaCO3). Calculate the concentrations of carbonic acid, bicarbonate ion 1HCO3-2 and carbonate ion 1CO32 - 2 that are in a raindrop that has a pH of 5.60, assuming that the sum of all three species in the raindrop is 1.0 * 10-5 M.

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Textbook Question

The acid–base indicator bromcresol green is a weak acid. The yellow acid and blue base forms of the indicator are present in equal concentrations in a solution when the pH is 4.68. What is the pKa for bromcresol green?

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Textbook Question

A sample of 0.2140 g of an unknown monoprotic acid was dissolved in 25.0 mL of water and titrated with 0.0950 M NaOH. The acid required 30.0 mL of base to reach the equivalence point. (a) What is the molar mass of the acid?

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Textbook Question

A sample of 0.1687 g of an unknown monoprotic acid was dissolved in 25.0 mL of water and titrated with 0.1150 M NaOH. The acid required 15.5 mL of base to reach the equivalence point. (b) After 7.25 mL of base had been added in the titration, the pH was found to be 2.85. What is the Ka for the unknown acid?

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Textbook Question
Mathematically prove that the pH at the halfway point of a titration of a weak acid with a strong base (where the volume of added base is half of that needed to reach the equivalence point) is equal to pKa for the acid.
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