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Ch.21 - Transition Elements and Coordination Chemistry

Chapter 21, Problem 21.128a

There are two possible [M(OH)4]- complexes of first-series transition metals that have three unpaired electrons.

(a) What are the oxidation state and the identity of M in these complexes?

(b) Using orbital diagrams, give a valence bond description of the bonding in each complex.

(c) Based on common oxidation states of first-series transition metals (Figure 21.6), which [M(OH)4]- complex is more likely to exist? 

<QUESTION REFERENCES FIGURE 21.6>-

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