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Ch.11 - Liquids & Phase Changes
Chapter 11, Problem 100

Draw a phase diagram showing how the phase boundaries differ for a pure solvent compared with a solution.Phase diagram comparing pure solvent and solution phases under varying pressure and temperature.
Phase diagram comparing pure solvent and solution phases under varying pressure and temperature.
Phase diagram comparing pure solvent and solution phases under varying pressure and temperature.

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1
Identify the phase boundaries for the pure solvent and the solution on the phase diagram.
Note that the phase boundaries for the solution are shifted compared to the pure solvent.
Observe that the freezing point of the solution is lower than that of the pure solvent, indicating freezing point depression.
Observe that the boiling point of the solution is higher than that of the pure solvent, indicating boiling point elevation.
Draw the phase diagram with the phase boundaries for the pure solvent and the solution, clearly labeling the solid, liquid, and gas regions for both.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Phase Diagram

A phase diagram is a graphical representation that shows the phases of a substance as a function of temperature and pressure. It illustrates the boundaries between different phases (solid, liquid, gas) and indicates the conditions under which each phase is stable. Understanding phase diagrams is crucial for analyzing how substances behave under varying environmental conditions.
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Colligative Properties

Colligative properties are properties of solutions that depend on the number of solute particles in a given amount of solvent, rather than the identity of the solute. These properties include boiling point elevation, freezing point depression, vapor pressure lowering, and osmotic pressure. They play a significant role in understanding how the addition of solute affects the phase behavior of a solvent.
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Phase Boundaries

Phase boundaries are the lines on a phase diagram that separate different phases of a substance. They indicate the conditions (temperature and pressure) at which two phases can coexist in equilibrium. In the context of pure solvents and solutions, the phase boundaries differ due to the presence of solute, which alters the physical properties and stability of the phases.
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Related Practice
Textbook Question
For each of the following substances, identify the intermolecular force or forces that predominate. Using your knowledge of the relative strengths of the various forces, rank the substances in order of their normal boiling points: Al2O3, F2, H2O, Br2, ICl, NaCl.
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1,3-Propanediol can form intramolecular as well as intermolecular hydrogen bonds. Draw a structure of 1,3-propanediol showing an intramolecular hydrogen bond.

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Textbook Question
Dimethyl ether has the following structure.

(b) Which of the following illustrations depicts the hydrogen bonding that occurs between dimethyl ether and water? (i)

(ii)

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Textbook Question
Just as individual bonds in a molecule are often polar, molecules as a whole are also often polar because of the net sum of individual bond polarities. There are three possible structures for substances with the formula C2H2Cl2, two of which are polar overall and one of which is not. (b) Which of the three structures is nonpolar, and which two are polar? Explain.
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Has the Earth's surface experienced warming as a result of increasing levels of greenhouse gases? If so, by how much?
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Textbook Question
Propanol (PrOH) and methyl methacrylate (MMA) asso-ciate in solution by an intermolecular force, forming an adduct represented as PrOH•MMA. The equilibrium con- stant for the association reaction is Kc = 0.701 at 298 K. (b) Draw a plausible structure for the PrOH • MMA adduct. Use to signify an intermolecular interaction.
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