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Ch.13 - Properties of Solutions
Chapter 13, Problem 98c

Acetonitrile (CH3CN) is a polar organic solvent that dissolves a wide range of solutes, including many salts. The density of a 1.80 M LiBr solution in acetonitrile is 0.826 g/cm3. Calculate the concentration of the solution in (c) mass percentage of CH3CN.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Molarity and Concentration

Molarity (M) is a measure of concentration defined as the number of moles of solute per liter of solution. In this case, a 1.80 M LiBr solution indicates that there are 1.80 moles of lithium bromide dissolved in one liter of acetonitrile. Understanding molarity is essential for converting between moles and mass when calculating mass percentages.
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Mass Percentage

Mass percentage is a way to express the concentration of a component in a mixture, calculated as the mass of the component divided by the total mass of the solution, multiplied by 100. To find the mass percentage of acetonitrile in the solution, one must determine the mass of acetonitrile and the total mass of the solution, which includes both the solute and the solvent.
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Density and Volume Relationships

Density is defined as mass per unit volume (g/cm³). In this problem, the density of the solution allows for the conversion between mass and volume. By knowing the density of the 1.80 M LiBr solution, one can calculate the total mass of the solution, which is necessary for determining the mass percentage of acetonitrile.
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Related Practice
Textbook Question

The maximum allowable concentration of lead in drinking water is 9.0 ppb. (b) How many grams of lead are in a swimming pool containing 9.0 ppb lead in 60 m3 of water?

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Textbook Question

Acetonitrile (CH3CN) is a polar organic solvent that dissolves a wide range of solutes, including many salts. The density of a 1.80 M LiBr solution in acetonitrile is 0.826 g/cm3. Calculate the concentration of the solution in (a) molality,

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Textbook Question

Acetonitrile (CH3CN) is a polar organic solvent that dissolves a wide range of solutes, including many salts. The density of a 1.80 M LiBr solution in acetonitrile is 0.826 g/cm3. Calculate the concentration of the solution in (b) mole fraction of LiBr,

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Textbook Question
A 'canned heat' product used to warm buffet dishes consists of a homogeneous mixture of ethanol 1C2H5OH2 and paraffin, which has an average formula of C24H50. What mass of C2H5OH should be added to 620 kg of the paraffin to produce 8 torr of ethanol vapor pressure at 35 °C? The vapor pressure of pure ethanol at 35 °C is 100 torr.
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Textbook Question

Two beakers are placed in a sealed box at 25 °C. One beaker contains 30.0 mL of a 0.050 M aqueous solution of a nonvolatile nonelectrolyte. The other beaker contains 30.0 mL of a 0.035 M aqueous solution of NaCl. The water vapor from the two solutions reaches equilibrium. (a) In which beaker does the solution level rise, and in which one does it fall?

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Textbook Question

Two beakers are placed in a sealed box at 25 °C. One beaker contains 30.0 mL of a 0.050 M aqueous solution of a nonvolatile nonelectrolyte. The other beaker contains 30.0 mL of a 0.035 M aqueous solution of NaCl. The water vapor from the two solutions reaches equilibrium. (b) What are the volumes in the two beakers when equilibrium is attained, assuming ideal behavior?

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