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Ch.18 - Thermodynamics: Entropy, Free Energy & Equilibrium

Chapter 18, Problem 143l

Methanol (CH3OH) is made industrially in two steps from CO and H2. It is so cheap to make that it is being considered for use as a precursor to hydrocarbon fuels, such as methane (CH4):

Step 1. CO(g) + 2 H2(g) S CH3OH(l) ΔS° = - 332 J/K

Step 2. CH3OH1l2 → CH4(g) + 1/2 O2(g) ΔS° = 162 J/K

(l) Is the overall reaction spontaneous at 298 K?

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