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Ch.5 - Gases
Chapter 5, Problem 113

A 160.0-L helium tank contains pure helium at a pressure of 1855 psi and a temperature of 298 K. How many 3.5-L helium balloons can be filled with the helium in the tank? (Assume an atmospheric pressure of 1.0 atm and a temperature of 298 K.)

Verified step by step guidance
1
Convert the pressure in the tank from psi to atm using the conversion factor: 1 atm = 14.7 psi.
Use the ideal gas law \( PV = nRT \) to calculate the number of moles of helium in the tank. Use the converted pressure in atm, the volume of the tank in liters, the temperature in Kelvin, and the ideal gas constant \( R = 0.0821 \text{ L atm K}^{-1} \text{ mol}^{-1} \).
Calculate the volume of helium at atmospheric pressure using the ideal gas law again, with the number of moles calculated in the previous step, atmospheric pressure, and the same temperature.
Determine the volume of helium available at atmospheric pressure by using the ratio of the initial and final pressures and volumes.
Divide the total volume of helium at atmospheric pressure by the volume of one balloon (3.5 L) to find the number of balloons that can be filled.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of a gas through the equation PV = nRT. This law is essential for understanding how gases behave under different conditions and allows us to calculate the amount of gas in a given volume at a specific pressure and temperature.
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Conversion of Units

In this problem, it is crucial to convert pressure from psi to atm and volume from liters to a consistent unit. Understanding how to convert between different units of measurement ensures accurate calculations and comparisons, particularly when dealing with gas laws and conditions.
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Stoichiometry of Gases

Stoichiometry in the context of gases involves calculating the relationships between the volumes of gases and their moles. By knowing the volume of helium available and the volume of each balloon, we can determine how many balloons can be filled, applying the principles of gas behavior and conservation of mass.
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Related Practice
Open Question
Gaseous ammonia is injected into the exhaust stream of a coal-burning power plant to reduce the pollutant NO to N2 according to the reaction: 4 NH3(g) + 4 NO(g) + O2(g) → 4 N2(g) + 6 H2O(g). Suppose that the exhaust stream of a power plant has a flow rate of 335 L/s at a temperature of 955 K, and that the exhaust contains a partial pressure of NO of 22.4 torr. What should be the flow rate of ammonia delivered at 755 torr and 298 K into the stream to react completely with the NO if the ammonia is 65.2% pure (by volume)?
Textbook Question

An ordinary gasoline can measuring 30.0 cm by 20.0 cm by 15.0 cm is evacuated with a vacuum pump. Assuming that virtually all of the air can be removed from inside the can and that atmospheric pressure is 14.7 psi, what is the total force (in pounds) on the surface of the can? Do you think that the can could withstand the force?

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Open Question
Twenty-five milliliters of liquid nitrogen (density = 0.807 g/mL) is poured into a cylindrical container with a radius of 10.0 cm and a length of 20.0 cm. The container initially contains only air at a pressure of 760.0 mmHg (atmospheric pressure) and a temperature of 298 K. If the liquid nitrogen completely vaporizes, what is the total force (in lb) on the interior of the container at 298 K?
Textbook Question

An 11.5-mL sample of liquid butane (density = 0.573 g/mL) is evaporated in an otherwise empty container at a temperature of 28.5 °C. The pressure in the container following evaporation is 892 torr. What is the volume of the container?

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Textbook Question

A scuba diver creates a spherical bubble with a radius of 2.5 cm at a depth of 30.0 m where the total pressure (including atmospheric pressure) is 4.00 atm. What is the radius of the bubble when it reaches the surface of the water? (Assume that the atmospheric pressure is 1.00 atm and the temperature is 298 K.)

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Open Question
A particular balloon can be stretched to a maximum surface area of 1257 cm². The balloon is filled with 3.0 L of helium gas at a pressure of 755 torr and a temperature of 298 K. The balloon is then allowed to rise in the atmosphere. If the atmospheric temperature is 273 K, what pressure will the balloon burst at? (Assume the balloon is the shape of a sphere.)