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Ch.7 - Thermochemistry
Chapter 7, Problem 49

How much heat is required to warm 2.50 L of water from 25.0 °C to 100.0 °C? (Assume a density of 1.0 g/mL for the water.)

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Convert the volume of water from liters to milliliters: 2.50 L = 2500 mL.
Use the density of water to find the mass: mass = volume \times density = 2500 \text{ mL} \times 1.0 \text{ g/mL}.
Calculate the temperature change (\Delta T): \Delta T = 100.0 \degree C - 25.0 \degree C.
Use the specific heat capacity of water (c = 4.18 \text{ J/g°C}) to set up the heat equation: q = m \times c \times \Delta T.
Substitute the values for mass, specific heat capacity, and temperature change into the equation to find the heat (q) required.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Specific Heat Capacity

Specific heat capacity is the amount of heat required to raise the temperature of one gram of a substance by one degree Celsius. For water, this value is approximately 4.18 J/g°C. Understanding this concept is crucial for calculating the heat required to change the temperature of water, as it directly relates the mass of the water and the temperature change to the total heat absorbed or released.
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Mass of Water

To calculate the heat required, we first need to determine the mass of the water. Given the volume of water (2.50 L) and the density (1.0 g/mL), we can convert the volume to mass using the formula: mass = volume × density. This step is essential because the specific heat capacity is defined per gram, so knowing the mass allows us to apply the specific heat formula accurately.
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Heat Transfer Equation

The heat transfer equation, often expressed as q = m × c × ΔT, relates the heat (q) absorbed or released to the mass (m) of the substance, its specific heat capacity (c), and the change in temperature (ΔT). In this scenario, ΔT is the difference between the final and initial temperatures of the water. This equation is fundamental for solving the problem, as it provides a direct method to calculate the total heat required for the temperature change.
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Related Practice
Textbook Question

The air in an inflated balloon (defined as the system) warms over a toaster and absorbs 142 J of heat. As it expands, it does 46 kJ of work. What is the change in internal energy for the system?

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Textbook Question

We pack two identical coolers for a picnic, placing 24 12-ounce soft drinks and five pounds of ice in each. However, the drinks that we put into cooler A were refrigerated for several hours before they were packed in the cooler, while the drinks that we put into cooler B were at room temperature. When we open the two coolers three hours later, most of the ice in cooler A is still present, while nearly all of the ice in cooler B has melted. Explain this difference.

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Textbook Question

A kilogram of aluminum metal and a kilogram of water are each warmed to 75 °C and placed in two identical insulated containers. One hour later, the two containers are opened and the temperature of each substance is measured. The aluminum has cooled to 35 °C, while the water has cooled only to 66 °C. Explain this difference.

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Textbook Question

How much heat is required to warm 2.50 kg of sand from 25.0 °C to 100.0 °C?

Textbook Question

Suppose that 25 g of each substance is initially at 27.0 °C. What is the final temperature of each substance upon absorbing 2.35 kJ of heat? c. aluminum

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Textbook Question

An unknown mass of each substance, initially at 23.0 °C, absorbs 1.95 × 103 J of heat. The final temperature is recorded. Find the mass of each substance.

a. Pyrex glass (Tf = 55.4°C)

b. sand (Tf = 62.1°C)

c. ethanol (Tf = 44.2°C)

d. water (Tf = 32.4°C)

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