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Ch.5 - Thermochemistry
Chapter 5, Problem 44c

Consider the following reaction: 2 CH3OH(g) → 2 CH4(g) + O2(g) ΔH = +252.8 kJ (c) For a given sample of CH3OH, the enthalpy change during the reaction is 82.1 kJ. How many grams of methane gas are produced?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced equation. It allows us to determine the relationships between the amounts of substances involved. In this case, the stoichiometric coefficients indicate that 2 moles of CH3OH produce 2 moles of CH4, establishing a 1:1 ratio for their quantities.
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Enthalpy Change (ΔH)

Enthalpy change (ΔH) represents the heat absorbed or released during a chemical reaction at constant pressure. A positive ΔH indicates an endothermic reaction, meaning energy is absorbed. In this reaction, the given ΔH of +252.8 kJ signifies that 2 moles of CH3OH absorb this amount of energy to produce the products.
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Molar Mass

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). It is essential for converting between moles and grams. For methane (CH4), the molar mass is approximately 16.04 g/mol, which will be used to calculate the mass of methane produced based on the moles derived from the enthalpy change.
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Related Practice
Textbook Question

Without referring to tables, predict which of the following has the higher enthalpy in each case: (c) 1 mol I2(g) and 1 mol H2(g) at 25 °C or 2 mol HI(g) at 25 °C (d) 1 mol H2(g) at 100 °C or 1 mol H2(g) at 300 °C.

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Open Question
Consider the following reaction: 2 Mg(s) + O₂(g) → 2 MgO(s) ΔH = -1204 kJ (b) Calculate the amount of heat transferred when 3.55 g of Mg(s) reacts at constant pressure. (d) How many kilojoules of heat are absorbed when 40.3 g of MgO(s) is decomposed into Mg(s) and O₂(g) at constant pressure?
Textbook Question

Consider the following reaction: 2 CH3OH(g) → 2 CH4(g) + O2(g) ΔH = +252.8 kJ (b) Calculate the amount of heat transferred when 24.0 g of CH3OH(g) is decomposed by this reaction at constant pressure.

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Textbook Question

Consider the following reaction: 2 CH3OH(g) → 2 CH4(g) + O2(g) ΔH = +252.8 kJ (d) How many kilojoules of heat are released when 38.5 g of CH4(g) reacts completely with O2(g) to form CH3OH(g) at constant pressure?

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Textbook Question

When solutions containing silver ions and chloride ions are mixed, silver chloride precipitates Ag+(aq) + Cl-(aq) → AgCl(s) H = -65.5 kJ (a) Calculate H for the production of 0.450 mol of AgCl by this reaction. (b) Calculate H for the production of 9.00 g of AgCl. (c) Calculate H when 9.25⨉10-4 mol of AgCl dissolves in water.

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Textbook Question

At one time, a common means of forming small quantities of oxygen gas in the laboratory was to heat KClO3: 2 KClO3(s) → 2 KCl(s) + 3 O2(g) ΔH = -89.4 kJ For this reaction, calculate H for the formation of (a) 1.36 mol of O2

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