So when comparing KP to KC, it's important to understand the value of ΞN. Here we're going to say the value of ΞN can determine if KC is greater than, less than, or equal to KP. Remember the equation is KP equals KCRT to the ΞN. ΞN represents the moles of gas as products minus the moles of gas as reactants.
We can solve it mathematically to see how KP and KC relate to one another if we know what ΞN is. Or we can just simply say if more moles of gas are being produced. So basically you start out with let's say 3 moles of gases reactants and you end up with four moles of gases reactants. Your number of moles of gas has increased. So if more moles of gas are produced, that would mean that ΞN would be equal to or greater than one. Then that would mean KP is greater than KC.
So here just remember if ΞN is greater than or equal to 1 then KP is greater than KC or KC is less than KP. If ΞN is less than 0 then KC is greater than KP and if it's equal to 0 then they're equal to one another. Now why is that? Well if we do KP equals KCRT to the ΞN and we make ΞN equal to 0. Remember, anything to the zero power equals one. So KP equals KC times one. Anything times one is equal to itself. So KP equals KC.
So again, we can mathematically figure out what ΞN is to see what the relationship between KC and KP is. And remember this relationship. Or you can just simply say that if you have a certain number of moles of gases, reactants and if you go to the product side, there's even more moles of gas product, that means that KP is going to be larger than KC. OK. So just you can use that type of logic in order to subvert the math and just look at the question itself in a qualitative matter.
Alright, so let's put to practice what we just learned in the following example and practice questions.