Ch.14 - Chemical Kinetics
Chapter 14, Problem 72c
The decomposition of hydrogen peroxide is catalyzed by iodide ion. The catalyzed reaction is thought to proceed by a two-step mechanism:
H2O2(aq) + I-(aq) → H2O(l) + IO-(aq) (slow)
IO-(aq) + H2O2(aq) → H2O(l) + O2(g) + I-(aq) (fast)
(c) Assuming that the first step of the mechanism is rate determining, predict the rate law for the overall process.
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