Skip to main content
Ch.14 - Chemical Kinetics
Chapter 14, Problem 98

What fraction of the film is left after 10 s, assuming the same initial coverage as in part a, given that the evaporation of a 120-nm film of n-pentane from a single crystal of aluminum oxide is zero order with a rate constant of 1.92 * 10^13 molecules/cm^2 * s at 120 K?

Verified step by step guidance
1
Identify that the problem involves zero-order kinetics, where the rate of reaction is constant and does not depend on the concentration of the reactant.
Use the zero-order rate equation: \[ [A] = [A]_0 - kt \] where \([A]\) is the concentration at time \(t\), \([A]_0\) is the initial concentration, \(k\) is the rate constant, and \(t\) is the time.
Determine the initial concentration \([A]_0\) in terms of molecules/cm². Since the problem states the initial coverage is the same as in part a, use that initial concentration value.
Substitute the given rate constant \(k = 1.92 \times 10^{13}\) molecules/cm²·s and the time \(t = 10\) s into the zero-order rate equation.
Calculate the concentration \([A]\) at \(t = 10\) s and then find the fraction of the film remaining by dividing \([A]\) by \([A]_0\).
Related Practice
Open Question
The desorption (leaving of the surface) of a single molecular layer of n-butane from a single crystal of aluminum oxide is found to be first order with a rate constant of 0.128 s−1 at 150 K. If the surface is initially completely covered, what fraction will remain covered after 10 s? After 20 s?
Textbook Question

The desorption (leaving of the surface) of a single molecular layer of n-butane from a single crystal of aluminum oxide is found to be first order with a rate constant of 0.128/s at 150 K. a. What is the half-life of the desorption reaction?-

873
views
Textbook Question

The desorption (leaving of the surface) of a single molecular layer of n-butane from a single crystal of aluminum oxide is found to be first order with a rate constant of 0.128/s at 150 K. b. If the surface is initially completely covered with n-butane at 150 K, how long will it take for 25% of the molecules to desorb (leave the surface)? For 50% to desorb?

654
views
Textbook Question

The evaporation of a 120-nm film of n-pentane from a single crystal of aluminum oxide is zero order with a rate constant of 1.92⨉1013 molecules/cm2•s at 120 K. a. If the initial surface coverage is 8.9⨉1016 molecules/cm2, how long will it take for one-half of the film to evaporate?

881
views
1
rank
Textbook Question

The kinetics of this reaction were studied as a function of temperature. (The reaction is first order in each reactant and second order overall.)

C2H5Br(aq) + OH- (aq) → C2H5OH(l) + Br- (aq)

Temperature (°C) k (L,mol •s)

25 8.81⨉10-5

35 0.000285

45 0.000854

55 0.00239

65 0.00633

a. Determine the activation energy and frequency factor for the reaction.

Textbook Question

The kinetics of this reaction were studied as a function of temperature. (The reaction is first order in each reactant and second order overall.)

C2H5Br(aq) + OH- (aq) → C2H5OH(l) + Br- (aq)

Temperature (°C) k (L,mol •s)

25 8.81⨉10-5

35 0.000285

45 0.000854

55 0.00239

65 0.00633

b. Determine the rate constant at 15 °C.

1072
views