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Ch.10 - Gases
Chapter 10, Problem 73

A quantity of N2 gas originally held at 5.25 atm pressure in a 1.00-L container at 26°C is transferred to a 12.5-L container at 20°C. A quantity of O2 gas originally at 5.25 atm and 26°C in a 5.00-L container is transferred to this same container. What is the total pressure in the new container?

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<Step 1: Use the ideal gas law to find the number of moles of N2 gas.> \( PV = nRT \) where \( P = 5.25 \text{ atm}, V = 1.00 \text{ L}, R = 0.0821 \text{ L atm K}^{-1} \text{ mol}^{-1}, T = 26°C = 299 \text{ K} \). Solve for \( n \).
<Step 2: Use the ideal gas law to find the number of moles of O2 gas.> \( PV = nRT \) where \( P = 5.25 \text{ atm}, V = 5.00 \text{ L}, R = 0.0821 \text{ L atm K}^{-1} \text{ mol}^{-1}, T = 26°C = 299 \text{ K} \). Solve for \( n \).
<Step 3: Calculate the total number of moles of gas in the new container by adding the moles of N2 and O2.>
<Step 4: Use the ideal gas law to find the total pressure in the new container.> \( P_{\text{total}}V = n_{\text{total}}RT \) where \( V = 12.5 \text{ L}, R = 0.0821 \text{ L atm K}^{-1} \text{ mol}^{-1}, T = 20°C = 293 \text{ K} \). Solve for \( P_{\text{total}} \).
<Step 5: Ensure all units are consistent and check calculations for accuracy.>

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law, represented as PV = nRT, relates the pressure (P), volume (V), and temperature (T) of an ideal gas to the number of moles (n) and the ideal gas constant (R). This law is fundamental for calculating changes in gas conditions, allowing us to determine how pressure varies with volume and temperature.
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Dalton's Law of Partial Pressures

Dalton's Law states that in a mixture of non-reacting gases, the total pressure exerted is equal to the sum of the partial pressures of each individual gas. This principle is crucial for calculating the total pressure in a container after transferring gases, as it allows us to consider the contributions of each gas separately.
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Gas Behavior under Changing Conditions

Gases behave differently under varying conditions of temperature and volume. When a gas is transferred to a new container with a different volume and temperature, its pressure will change according to the Ideal Gas Law. Understanding how these variables interact is essential for predicting the final pressure in the new container.
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Related Practice
Textbook Question

(a) What are the mole fractions of O2 in a mixture of 15.08 g of O2, 8.17 g of N2, and 2.64 g of H2?

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Textbook Question

(a) What are the mole fractions of N2 in a mixture of 15.08 g of O2, 8.17 g of N2, and 2.64 g of H2?

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Textbook Question

(a) What are the mole fractions of H2 in a mixture of 15.08 g of O2, 8.17 g of N2, and 2.64 g of H2?

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Textbook Question

A sample of 3.00 g of SO2(g) originally in a 5.00-L vessel at 21 °C is transferred to a 10.0-L vessel at 26 °C. A sample of 2.35 g of N2(g) originally in a 2.50-L vessel at 20 °C is transferred to this same 10.0-L vessel. (a) What is the partial pressure of SO2(g) in the larger container? (b) What is the partial pressure of N2(g) in this vessel?

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Textbook Question

Determine whether each of the following changes will increase, decrease, or not affect the rate with which gas molecules collide with the walls of their container: (a) increasing the volume of the container (b) increasing the temperature (c) increasing the molar mass of the gas

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Textbook Question

Indicate which of the following statements regarding the kinetic-molecular theory of gases are correct. (a) The average kinetic energy of a collection of gas molecules at a given temperature is proportional to m1/2. (b) The gas molecules are assumed to exert no forces on each other. (c) All the molecules of a gas at a given temperature have the same kinetic energy. (d) The volume of the gas molecules is negligible in comparison to the total volume in which the gas is contained. (e) All gas molecules move with the same speed if they are at the same temperature.

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