15. Chemical Kinetics
Reaction Mechanism
5:43 minutes
Problem 114a
Textbook Question
Textbook QuestionA proposed mechanism for the oxidation of nitric oxide to nitrogen dioxide was described in Problem 14.29. Another possible mechanism for this reaction is 2 NO1g2 k1 k-1 N2O21g2 Faster, reversible N2O21g2 + O21g2 ¡ k2 2NO21g2 Slower, rate-determining (b) Show that this mechanism is consistent with the experimental rate law, Rate = k3NO423O24.
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