Ch.18 - Thermodynamics: Entropy, Free Energy & Equilibrium
All textbooksMcMurry 8th EditionCh.18 - Thermodynamics: Entropy, Free Energy & EquilibriumProblem 56a
Chapter 18, Problem 56a
Which state in each of the following pairs has the higher entropy per mole of substance? (a) H2 at 25 °C in a volume of 10 L or H2 at 25 °C in a volume of 50 L
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Textbook Question
When rolling a pair of dice, there are two ways to get a point total of 3(1+2;2+1) but only one way to get a point total of 2(1+1). How many ways are there of getting point totals of 4 to 12? What is the most probable point total?
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Textbook Question
Consider the distribution of ideal gas molecules among three bulbs (A, B, and C) of equal volume. For each of the follow-ing states, determine the number of ways (W) that the state can be achieved, and use Boltzmann's equation to calculate the entropy of the state.
(a) 2 molecules in bulb A
(b) 2 molecules randomly distributed among bulbs A, B, and C
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Textbook Question
Which state has higher entropy? Explain in terms of probability.
(a) A perfectly ordered crystal of solid nitrous oxide or a disordered crystal in which the molecules are oriented randomly
(b) Quartz glass (an amorphous solid) or a quartz crystal
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Textbook Question
Which state in each of the following pairs has the higher entropy per mole of substance? (d) CO2 at STP or CO2 at 100 °C and 0.1 atm
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Textbook Question
Which state in each of the following pairs has the higher entropy per mole of substance? (a) Ice at -40 °C or ice at 0 °C
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Textbook Question
Which state in each of the following pairs has the higher entropy per mole of substance? (b) N2 at STP or N2 at 0 °C and 10 atm
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