Use data from Appendix IIB to calculate ΔS°rxn for each of the reactions. In each case, try to rationalize the sign of ΔS°rxn. c. SO2(g) + 1/2 O2(g) → SO3(g)
Ch.18 - Free Energy and Thermodynamics
Chapter 18, Problem 58
What is ΔS° for the reaction between nitrogen gas and fluorine gas to form nitrogen trifluoride gas, and how can the sign of ΔS° be rationalized?
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<insert step 1> Identify the balanced chemical equation for the reaction: \( N_2(g) + 3F_2(g) \rightarrow 2NF_3(g) \).
<insert step 2> Determine the standard molar entropy (S°) values for each substance involved in the reaction from a reliable data source.
<insert step 3> Calculate the change in standard entropy (ΔS°) for the reaction using the formula: \( \Delta S^\circ = \sum S^\circ_{\text{products}} - \sum S^\circ_{\text{reactants}} \).
<insert step 4> Substitute the standard molar entropy values into the formula to find ΔS°.
<insert step 5> Rationalize the sign of ΔS° by considering the change in the number of gas molecules: the reaction goes from 4 moles of gas (1 mole of \(N_2\) and 3 moles of \(F_2\)) to 2 moles of \(NF_3\), indicating a decrease in entropy.>
Related Practice
Textbook Question
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Textbook Question
Use data from Appendix IIB to calculate ΔS°rxn for each of the reactions. In each case, try to rationalize the sign of ΔS°rxn. d. N2O4(g) + 4 H2(g) → N2(g) + 4 H2O(g)
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Textbook Question
Find ΔS° for the formation of CH2Cl2(g) from its gaseous elements in their standard states. Rationalize the sign of ΔS°.
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Textbook Question
Methanol (CH3OH) burns in oxygen to form carbon dioxide and water. Write a balanced equation for the combustion of liquid methanol and calculate ΔH°rxn, ΔS°rxn, and ΔG°rxn at 25 °C. Is the combustion of methanol spontaneous?
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Textbook Question
In photosynthesis, plants form glucose (C6H12O6) and oxygen from carbon dioxide and water. Write a balanced equation for photosynthesis and calculate ΔH°rxn, ΔS°rxn, and ΔG°rxn at 25 °C. Is photosynthesis spontaneous?
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Open Question
For each reaction, calculate ΔH°rxn, ΔS°rxn, and ΔG°rxn at 25 °C and state whether the reaction is spontaneous. If the reaction is not spontaneous, would a change in temperature make it spontaneous? If so, should the temperature be raised or lowered from 25 °C?
b. NH4Cl(s) → HCl(g) + NH3(g)
c. 3 H2(g) + Fe2O3(s) → 2 Fe(s) + 3 H2O(g)