Chapter 20, Problem 100c
Gold exists in two common positive oxidation states, +1 and +3. The standard reduction potentials for these oxidation states are Au+1aq2 + e- ¡ Au1s2 Ered ° = +1.69 V Au3+1aq2 + 3 e- ¡ Au1s2 Ered ° = +1.50 V (c) Miners obtain gold by soaking gold-containing ores in an aqueous solution of sodium cyanide. A very soluble complex ion of gold forms in the aqueous solution because of the redox reaction 4 Au1s2 + 8 NaCN1aq2 + 2 H2O1l2 + O21g2 ¡ 4 Na3Au1CN2241aq2 + 4 NaOH1aq2 What is being oxidized, and what is being reduced in this reaction?
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A disproportionation reaction is an oxidation–reduction reaction in which the same substance is oxidized and reduced. Complete and balance the following disproportionation reactions: (b) MnO42-(aq) → MnO4-(aq) + MnO2(s) (acidic solution)
Predict whether the following reactions will be spontaneous in acidic solution under standard conditions: (c) reduction of Ce4+ to Ce3+ by H2O2,
A voltaic cell is constructed that uses the following half-cell reactions: Cu+1aq2 + e- ¡ Cu1s2 I21s2 + 2 e- ¡ 2 I-1aq2 The cell is operated at 298 K with 3Cu+4 = 0.25 M and 3I-4 = 0.035 M. (a) Determine E for the cell at these concentrations.
The capacity of batteries such as the typical AA alkaline battery is expressed in units of milliamp-hours (mAh). An AA alkaline battery yields a nominal capacity of 2850 mAh. (b) The starting voltage of a fresh alkaline battery is 1.55 V. The voltage decreases during discharge and is 0.80 V when the battery has delivered its rated capacity. If we assume that the voltage declines linearly as current is withdrawn, estimate the total maximum electrical work the battery could perform during discharge.