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Ch.8 - Basic Concepts of Chemical Bonding
Chapter 8, Problem 71a,c

State whether each of these statements is true or false. (a) The longer the bond, the stronger the bond. (c) A typical double bond length is in the 500–1000 pm range.

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Step 1: Understand the relationship between bond length and bond strength. Generally, shorter bonds are stronger because the atoms are closer together, leading to stronger attractive forces. Therefore, evaluate the statement 'The longer the bond, the stronger the bond' based on this understanding.
Step 2: Consider typical bond lengths for single, double, and triple bonds. Single bonds are generally longer than double bonds, which are longer than triple bonds. This is due to the increased number of shared electrons in multiple bonds, which pulls the atoms closer together.
Step 3: Evaluate the statement about double bond lengths. Typical double bond lengths are usually in the range of 120–140 pm (picometers), not 500–1000 pm. Compare this with known data for common double bonds, such as C=C or C=O.
Step 4: Use the information from Steps 1 and 2 to determine the truth value of statement (a). Since longer bonds are generally weaker, the statement 'The longer the bond, the stronger the bond' is false.
Step 5: Use the information from Step 3 to determine the truth value of statement (c). Since typical double bond lengths are much shorter than 500–1000 pm, the statement is false.

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There are many Lewis structures you could draw for sulfuric acid, H2SO4 (each H is bonded to an O). (b) What Lewis structure(s) would you draw to minimize formal charge?

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Some chemists believe that satisfaction of the octet rule should be the top criterion for choosing the dominant Lewis structure of a molecule or ion. Other chemists believe that achieving the best formal charges should be the top criterion. Consider the dihydrogen phosphate ion, H2PO4-, in which the H atoms are bonded to O atoms. (a) What is the predicted dominant Lewis structure if satisfying the octet rule is the top criterion?

Textbook Question

Some chemists believe that satisfaction of the octet rule should be the top criterion for choosing the dominant Lewis structure of a molecule or ion. Other chemists believe that achieving the best formal charges should be the top criterion. Consider the dihydrogen phosphate ion, H2PO4-, in which the H atoms are bonded to O atoms. (b) What is the predicted dominant Lewis structure if achieving the best formal charges is the top criterion?

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State whether each of these statements is true or false. (e) The longer the bond, the more energy is stored chemical bonds.

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Open Question
State whether each of these statements is true or false. (a) An oxygen–oxygen double bond is shorter than an oxygen–oxygen single bond. (b) The C—C bond in ethene is longer than the C—C bond in polyethene.
Open Question
We can define average bond enthalpies and bond lengths for ionic bonds, just like we have for covalent bonds. Which ionic bond is predicted to be stronger, Na—Cl or Ca—O?