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Ch.5 - Thermochemistry

Chapter 5, Problem 96

It is interesting to compare the 'fuel value' of a hydrocarbon in a hypothetical world where oxygen is not the combustion agent. The enthalpy of formation of CF4(g) is -679.9 kJ/mol. Which of the following two reactions is the more exothermic?

CH4(g) + 2 O2(g) → CO2(g) + 2 H2O(g)

CH4(g) + 4 F2(g) → CF4(g) + 4 HF(g)

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