Skip to main content
Ch.7 - Quantum-Mechanical Model of the Atom
Chapter 7, Problem 57

Which electron is, on average, closer to the nucleus: an electron in a 2s orbital or an electron in a 3s orbital?

Verified step by step guidance
1
Understand the concept of atomic orbitals and their energy levels. The principal quantum number, n, indicates the energy level and size of the orbital.
Recognize that the 2s orbital has a principal quantum number of n=2, while the 3s orbital has n=3.
Recall that orbitals with lower principal quantum numbers are generally closer to the nucleus.
Consider the radial distribution of s orbitals, which shows that electrons in lower energy levels (like 2s) are more likely to be found closer to the nucleus than those in higher energy levels (like 3s).
Conclude that, on average, an electron in a 2s orbital is closer to the nucleus than an electron in a 3s orbital due to the lower principal quantum number.