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Ch.8 - Basic Concepts of Chemical Bonding
Chapter 8, Problem 85d

Consider the collection of nonmetallic elements: B, As, O, and I. (d) Which element would likely to participate in two covalent bonds?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Covalent Bonding

Covalent bonding occurs when two atoms share one or more pairs of electrons, allowing them to achieve a more stable electron configuration. Nonmetals, which typically have high electronegativities, tend to form covalent bonds with other nonmetals. The number of covalent bonds an element can form is often determined by its valence electrons and its ability to share them with other atoms.
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Valence Electrons

Valence electrons are the outermost electrons of an atom and are crucial in determining how an element interacts with others. The number of valence electrons influences an element's bonding behavior; for instance, elements with four or more valence electrons can form multiple covalent bonds. Understanding the valence electron configuration of the elements in question helps predict their bonding capabilities.
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Nonmetallic Elements

Nonmetals are elements that typically lack the characteristics of metals, such as conductivity and malleability. They are found on the right side of the periodic table and often have high electronegativities, which allows them to form covalent bonds. Nonmetals like boron (B) and oxygen (O) can form multiple bonds due to their electron configurations, making them key players in covalent bonding scenarios.
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Related Practice
Open Question
A classmate of yours is convinced that he knows everything about electronegativity. (a) In the case of atoms X and Y having different electronegativities, he says, the diatomic molecule X–Y must be polar. Is your classmate correct? (b) Your classmate says that the farther the two atoms are apart in a bond, the larger the dipole moment will be. Is your classmate correct?
Textbook Question

Consider the collection of nonmetallic elements O, P, Te, I, and B. (a) Which two would form the most polar single bond?

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Textbook Question

Consider the collection of nonmetallic elements O, P, Te, I, and B. (b) Which two would form the longest single bond?

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Textbook Question

The substance chlorine monoxide, ClO(g), is important in atmospheric processes that lead to depletion of the ozone layer. The ClO molecule has an experimental dipole moment of 1.24 D, and the Cl — O bond length is 160 pm. (b) Based on the electronegativities of the elements, which atom would you expect to have a partial negative charge in the ClO molecule?

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Textbook Question

The substance chlorine monoxide, ClO(g), is important in atmospheric processes that lead to depletion of the ozone layer. The ClO molecule has an experimental dipole moment of 1.24 D, and the Cl—O bond length is 160 pm. (c) Using formal charges as a guide, propose the dominant Lewis structure for the molecule. (g), is important in atmospheric processes that lead to depletion of the ozone layer. The ClO molecule has an experimental dipole moment of 1.24 D, and the Cl—O bond length is 160 pm. (d) The anion ClO exists. What is the formal charge on the Cl for the best Lewis structure for ClO-?

Textbook Question

(a) Using the electronegativities of Br and Cl, estimate the partial charges on the atoms in the Br¬Cl molecule.