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Ch.5 - Periodicity & Electronic Structure of Atoms
Chapter 5, Problem 76

What are the four quantum numbers, and what does each specify?

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Identify the four quantum numbers: principal quantum number (n), azimuthal quantum number (l), magnetic quantum number (m_l), and spin quantum number (m_s).
Understand that the principal quantum number (n) specifies the energy level or shell of an electron within an atom. It can take positive integer values (n = 1, 2, 3, ...).
Recognize that the azimuthal quantum number (l) determines the shape of the electron's orbital and is dependent on n. It can take integer values from 0 to n-1. Each value of l corresponds to a specific type of orbital (s, p, d, f, etc.).
Learn that the magnetic quantum number (m_l) specifies the orientation of the orbital in space. It can take integer values ranging from -l to +l, including zero.
Note that the spin quantum number (m_s) indicates the direction of the electron's spin and can have values of +1/2 or -1/2, representing the two possible spin states of an electron.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Quantum Numbers

Quantum numbers are a set of four values that describe the unique quantum state of an electron in an atom. They provide essential information about the electron's energy level, shape of the orbital, orientation in space, and spin direction. Each quantum number corresponds to specific properties of the electron's behavior and location within an atom.
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Principal Quantum Number (n)

The principal quantum number (n) indicates the main energy level or shell of an electron in an atom. It is a positive integer (n = 1, 2, 3, ...) that determines the size and energy of the orbital. Higher values of n correspond to electrons that are further from the nucleus and have higher energy.
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Angular Momentum Quantum Number (l)

The angular momentum quantum number (l) defines the shape of the electron's orbital and can take on integer values from 0 to (n-1). Each value of l corresponds to a specific type of orbital: s (l=0), p (l=1), d (l=2), and f (l=3). This quantum number is crucial for understanding the distribution of electrons in different regions of an atom.
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