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Ch.14 - Chemical Kinetics

Chapter 14, Problem 99b

The kinetics of this reaction were studied as a function of temperature. (The reaction is first order in each reactant and second order overall.) C2H5Br(aq) + OH- (aq)¡C2H5OH(l ) + Br - (aq) Temperature (°C) k (L,mol # s) 25 8.81 * 10- 5 35 0.000285 45 0.000854 55 0.00239 65 0.00633 b. Determine the rate constant at 15 °C.

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