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Ch.10 - Gases

Chapter 10, Problem 52

(b) Calculate the molar mass of a vapor that has a density of 7.135 g>L at 12 °C and 99.06 kPa.

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Hey everyone in this example, we're told that a sample of gas is found to have a density of 1.457 g per liter at 34 degrees Celsius and 8 35 Tour. We need to determine the molar mass of this gas. So we're going to recall our density form of our ideal gas equation and we should recall that that is going to be equal to our density symbol, which is rho equal to our pressure of our gas, multiplied by its molar mass and then divided by the gas constant R. Times temperature. Now, in terms of this question, we need to solve for Mueller mass. So we're going to reorganize this to solve for Mueller mass so that we have Mueller mass equal to our density of our gas, multiplied by the gas constant R. Times temperature and then divided by pressure of our gas. Before we go ahead and plug in our known values. We need to recognize that we're going to have to convert our pressure value from Tour to A. T. M. Because that's the proper unit for pressure in this equation. And we want to go ahead and also convert our temperature from Celsius to kelvin. So what we're going to do is start out by converting our pressure. So we're given the pressure of 835 tour and we want to go ahead and convert from Tour into a. T. M's by recalling our conversion factor that for 1 80 M we have 60 Tour. So now we're able to cancel out our units of tours leaving us with a T. M. As our pressure unit. And this is going to give us a pressure equal to 1.10 ATMs. Now moving on to our temperature, we want to go ahead and convert our temperature given from 34°C. And we're going to not multiply but rather add to 73 . Kelvin to convert to Kelvin. And this is going to give us our proper temperature equal to 307.15 Kelvin. So now we're able to go ahead and solve for molar mass. This is going to equal our density value given in the problem as 1.457 g/l. We're going to then multiply this by r. Gas constant R. Which we should recall is equal to 0.8206. Leaders times a T. M's, divided by moles, times kelvin. And then this is also multiplied by our temperature, which we converted to 307.15 Kelvin In our denominator. We're going to plug in our pressure, which we converted to ATM as 1.10 ATMs. So now we're going to cancel out our units. We can get rid of ATMs. We can get rid of leaders. Sorry, Leaders is over here. We can still get rid of kelvin's and this leaves us with gramps Per mole as our final units, which is what we would agree with for molar mass. And so what we would get is that our molar mass of our gas is equal to a value of 33.4 g per mole. And this is going to be our final answer to complete this example. So I hope that everything I explained was clear. If you have any questions, leave them down below and I will see everyone in the next practice video.
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Textbook Question

Which of the following statements best explains why a closed balloon filled with helium gas rises in air? (a) Helium is a monatomic gas, whereas nearly all the molecules that make up air, such as nitrogen and oxygen, are diatomic. (b) The average speed of helium atoms is greater than the average speed of air molecules, and the greater speed of collisions with the balloon walls propels the balloon upward. (c) Because the helium atoms are of lower mass than the average air molecule, the helium gas is less dense than air. The mass of the balloon is thus less than the mass of the air displaced by its volume. (d) Because helium has a lower molar mass than the average air molecule, the helium atoms are in faster motion. This means that the temperature of the helium is greater than the air temperature. Hot gases tend to rise.

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Textbook Question

(a) Calculate the density of NO2 gas at 0.970 atm and 35 °C.

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Textbook Question

(b) Calculate the molar mass of a gas if 2.50 g occupies 0.875 L at 685 torr and 35 °C

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Textbook Question
In the Dumas-bulb technique for determining the molar mass of an unknown liquid, you vaporize the sample of a liquid that boils below 100 °C in a boiling-water bath and determine the mass of vapor required to fill the bulb. From the following data, calculate the molar mass of the unknown liquid: mass of unknown vapor, 1.012 g; volume of bulb, 354 cm3; pressure, 98.93 kPa; temperature, 99 °C.
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Textbook Question
The molar mass of a volatile substance was determined by the Dumas-bulb method described in Exercise 10.53. The unknown vapor had a mass of 2.55 g; the volume of the bulb was 500 mL, pressure 101.33 kPa, and temperature 37 °C.Calculate the molar mass of the unknown vapor.
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Textbook Question
Magnesium can be used as a 'getter' in evacuated enclosures to react with the last traces of oxygen. (The magnesium is usually heated by passing an electric current through a wire or ribbon of the metal.) If an enclosure of 5.67 L has a partial pressure of O2 of 7.066 mPa at 30 °C, what mass of magnesium will react according to the following equation? 2 Mg1s2 + O21g2¡2 MgO1s2
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