Ch.14 - Chemical Kinetics
Chapter 14, Problem 33a
The iodide ion reacts with hypochlorite ion (the active ingredient in chlorine bleaches) in the following way: OCl- + I- → OI- + Cl- . This rapid reaction gives the following rate data:
[OCl4-] (M) [I-] (M) Initial Rate (M,s)
1.5 * 10-3 1.5 * 10-3
1.36 * 10-4 3.0 * 10-3 1.5 * 10-3 2.72 * 10-4
1.5 * 10-3 3.0 * 10-3 2.72 * 10-4
(a) Write the rate law for this reaction.
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