Skip to main content
Ch.9 - Molecular Geometry and Bonding Theories
Chapter 9, Problem 74a

Indicate whether each statement is true or false. (a) p orbitals can only make σ or σ* molecular orbitals.

Verified step by step guidance
1
Understand the nature of p orbitals: p orbitals are atomic orbitals with a dumbbell shape and can participate in forming molecular orbitals through linear combinations with other atomic orbitals.
Recall the types of molecular orbitals: Molecular orbitals can be classified as sigma (σ), sigma star (σ*), pi (π), and pi star (π*).
Consider the orientation of p orbitals: When two p orbitals overlap end-to-end along the internuclear axis, they form sigma (σ) or sigma star (σ*) molecular orbitals.
Consider the alternative overlap: When two p orbitals overlap side-by-side, they form pi (π) or pi star (π*) molecular orbitals.
Evaluate the statement: Since p orbitals can form both σ/σ* and π/π* molecular orbitals, the statement that p orbitals can only make σ or σ* molecular orbitals is false.

Verified Solution

Video duration:
46s
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?