Draw a picture that shows all three 2p orbitals on one atom and all three 2p orbitals on another atom. (a) Imagine the atoms coming close together to bond. How many σ bonds can the two sets of 2p orbitals make with each other?
Ch.9 - Molecular Geometry and Bonding Theories
Chapter 9, Problem 74a
Indicate whether each statement is true or false. (a) p orbitals can only make σ or σ* molecular orbitals.

1
Understand the nature of p orbitals: p orbitals are atomic orbitals with a dumbbell shape and can participate in forming molecular orbitals through linear combinations with other atomic orbitals.
Recall the types of molecular orbitals: Molecular orbitals can be classified as sigma (σ), sigma star (σ*), pi (π), and pi star (π*).
Consider the orientation of p orbitals: When two p orbitals overlap end-to-end along the internuclear axis, they form sigma (σ) or sigma star (σ*) molecular orbitals.
Consider the alternative overlap: When two p orbitals overlap side-by-side, they form pi (π) or pi star (π*) molecular orbitals.
Evaluate the statement: Since p orbitals can form both σ/σ* and π/π* molecular orbitals, the statement that p orbitals can only make σ or σ* molecular orbitals is false.

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