Here in this example question, it says a sample of gas initially has a volume of 900 milliliters at 520 Kelvin and 1.85 atmospheres. What is the pressure of the gas if the volume decreases to 330 milliliters while the temperature increases to 770 Kelvin?
All right. So in this question, they're giving me a volume. We're going to say it's V1 because later on they give me a second new volume V2. They give me a temperature T1 and then later give me a second temperature T2. They give me this pressure in atmosphere. So this is P1 because later they ask me what is the new pressure. So they're asking us to find P2.
Now we have our ideal gas law PV = nRT. If you have watched my videos on ideal law derivations, you know that we can manipulate the ideal gas law in order to get our combined gas law. Now, if you haven't watched those videos, I highly suggest you go back and take a look. So look under ideal gas Derivation videos.
Now here we're talking about two pressures. We're talking about two volumes. We're talking about two temperatures. Moles aren't being discussed because they're being held constant. R is a constant. We divide out the T so that everything is on the left side, and we see that since we're dealing with two different values for these variables, it becomes
P 1 V 1 T 1 = P 2 V 2 T 2So here we just showed how we derived the combined gas law.
All right, so now we're going to plug in the values that we have. Our pressure is 1.85 atmospheres initially. Our volume, when we change the milliliters to liters, it gives us 0.900 liters. Remember, temperature must always be in kelvins when doing calculations. It's already in Kelvin so we don't have to worry about that.
Equals. We don't know what P2 is. V2 is 0.330 liters and then temperature 2 is 770 Kelvin. We're just looking to isolate our P2 so you can cross multiply these and then you can cross multiply these so that you can isolate P2. So if I come over here, I'm going to see that
P 2 = P 1 × 0.330 liters × 520 Kelvin = 1.85 atmospheres × 0.900 liters × 770 KelvinSo divide out the volume and the temperature that we have here on both sides here. So we divide them both to both sides. By that we'll have isolated at the end our P2, so liters cancel out, Kelvin's cancel out and we'll see here that P2 = 7.47 atmospheres. We can see that by changing our volume and changing our temperature, it's caused this change in our pressure too, which comes out again to 7.47 atmospheres.