The dissolution of CaCl2(s) in water is exothermic, with ΔHsoln= - 81.3 kJ>mol. If you were to prepare a 1.00 m solution of CaCl2 beginning with water at 25.0 °C, what would the final temperature of the solution be in °C? Assume that the specific heats of both pure H2O and the solution are the same, 4.18 J>1K g2.
Ch.13 - Solutions & Their Properties
Chapter 13, Problem 59a
Residues of the herbicide atrazine (C8H14ClN5) in water can be detected at concentrations as low as 0.050 µg/L. Express this concentration of atrazine in the following units: (a) Parts per billion (assume a solution density of 1.00 g/mL)
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Understand that parts per billion (ppb) is a way to express very dilute concentrations of substances. It is defined as the mass of the solute divided by the mass of the solution, multiplied by 10^9.
Since the density of the solution is given as 1.00 g/mL, we can assume that 1 L of the solution has a mass of 1000 g (since 1 L = 1000 mL).
Convert the concentration from micrograms per liter (µg/L) to grams per liter (g/L) by recognizing that 1 µg = 10^-6 g. Therefore, 0.050 µg/L is equivalent to 0.050 x 10^-6 g/L.
Calculate the mass of atrazine in grams in 1 L of solution, which is 0.050 x 10^-6 g.
To find the concentration in ppb, divide the mass of atrazine in grams by the mass of the solution in grams (1000 g), and then multiply by 10^9 to convert to ppb.
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Textbook Question
Residues of the herbicide atrazine (C8H14ClN5) in water can be detected at concentrations as low as 0.050 µg/L. Express this concentration of atrazine in the following units: (b) Molarity
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