Skip to main content
Ch.20 - Electrochemistry
Chapter 20, Problem 6

Consider the following table of standard electrode potentials for a series of hypothetical reactions in an aqueous solution: reduction half-reaction E °(V) (c) Which substance(s) can oxidize C2+?

Verified step by step guidance
1
<insert step 1> Identify the reduction half-reaction for C^{2+} and note its standard electrode potential, E^\circ.>
<insert step 2> Understand that a substance can oxidize C^{2+} if it has a higher standard electrode potential than the C^{2+}/C half-reaction.>
<insert step 3> Review the table of standard electrode potentials provided in the problem.>
<insert step 4> Compare the E^\circ values of other substances with the E^\circ value of the C^{2+}/C half-reaction.>
<insert step 5> Identify the substances with higher E^\circ values than C^{2+}/C, as these can oxidize C^{2+}.>

Verified Solution

Video duration:
2m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Standard Electrode Potential

Standard electrode potential (E°) is a measure of the tendency of a chemical species to be reduced, expressed in volts. It indicates how easily a species can gain electrons in a half-reaction. A higher E° value means a greater ability to be reduced, while a lower E° indicates a stronger tendency to oxidize. Understanding these values is crucial for predicting the direction of redox reactions.
Recommended video:
Guided course
01:27
Standard Cell Potential

Oxidizing and Reducing Agents

In redox reactions, an oxidizing agent is a substance that gains electrons and is reduced, while a reducing agent loses electrons and is oxidized. To determine which substances can oxidize C2+, one must identify those with higher standard electrode potentials than C2+. This relationship is essential for predicting which species can facilitate the oxidation of another.
Recommended video:
Guided course
01:01
Oxidizing and Reducing Agents

Half-Reaction Method

The half-reaction method involves separating oxidation and reduction processes to analyze redox reactions. Each half-reaction can be assigned a standard electrode potential, allowing for the comparison of different species. By using this method, one can determine the feasibility of reactions and identify which substances can act as oxidizers or reducers based on their respective potentials.
Recommended video:
Guided course
01:49
Method 1 of Radioactive Half-Life
Related Practice
Textbook Question

Assume that you want to construct a voltaic cell that uses the following half-reactions: A2+1aq2 + 2 e- ¡ A1s2 Ered ° = -0.10 V B2+1aq2 + 2 e- ¡ B1s2 E°red = -1.10 V You begin with the incomplete cell pictured here in which the electrodes are immersed in water.

(a) What additions must you make to the cell for it to generate a standard emf?

660
views
Open Question
The standard reduction potential for the reduction of RuO4^-(aq) to RuO4^2-(aq) is +0.59 V. By using Appendix E, which of the following substances can oxidize RuO4^2-(aq) to RuO4^-(aq) under standard conditions: Br2(l), BrO3^-(aq), Mn^2+(aq), O2(g), Sn^2+(aq)?
Open Question
For a spontaneous reaction A1aq2 + B1aq2 → A-1aq2 + B+1aq2, answer the following questions: (a) If you made a voltaic cell out of this reaction, what half-reaction would be occurring at the cathode, and what half-reaction would be occurring at the anode?
Open Question
A voltaic cell is constructed with two silver–silver chloride electrodes, each of which is based on the following half-reaction: AgCl(s) + e- → Ag(s) + Cl-(aq). The two half-cells have [Cl-] = 0.0150 M and [Cl-] = 2.55 M, respectively. (c) What is the cell emf for the concentrations given? (d) For each electrode, predict whether [Cl-] will increase, decrease, or stay the same as the cell operates.
Textbook Question

Consider the following voltaic cell:

(c) What is the change in the cell voltage when the ion concentrations in the cathode half-cell are increased by a factor of 10?

757
views
Open Question
(a) What is an electrolytic cell? (b) The negative terminal of a voltage source is connected to an electrode of an electrolytic cell. Is the electrode the anode or the cathode of the cell? Explain.