Skip to main content
Ch.14 - Chemical Kinetics
Chapter 14, Problem 104

How old is a rock that contains 83.2% of the amount of uranium-238 it contained when it was formed?

Verified step by step guidance
1
<insert step 1> Determine the decay constant (\( \lambda \)) for uranium-238 using its half-life. The half-life of uranium-238 is approximately 4.5 billion years. Use the formula \( \lambda = \frac{0.693}{\text{half-life}} \).>
<insert step 2> Use the decay formula \( N = N_0 e^{-\lambda t} \), where \( N \) is the remaining quantity of uranium-238, \( N_0 \) is the initial quantity, \( \lambda \) is the decay constant, and \( t \) is the time elapsed.>
<insert step 3> Since the rock contains 83.2% of the original uranium-238, set \( N = 0.832 N_0 \). Substitute this into the decay formula to get \( 0.832 N_0 = N_0 e^{-\lambda t} \).>
<insert step 4> Simplify the equation to \( 0.832 = e^{-\lambda t} \).>
<insert step 5> Solve for \( t \) by taking the natural logarithm of both sides: \( \ln(0.832) = -\lambda t \). Rearrange to find \( t = \frac{\ln(0.832)}{-\lambda} \).>
Related Practice
Textbook Question

Consider the two reactions:

O + N2 → NO + N Ea = 315 kJ/mol

Cl + H2 → HCl + H Ea = 23 kJ/mol

a. Why is the activation barrier for the first reaction so much higher than that for the second?

561
views
Textbook Question

Consider the two reactions:

O + N2 → NO + N Ea = 315 kJ/mol

Cl + H2 → HCl + H Ea = 23 kJ/mol

b. The frequency factors for these two reactions are very close to each other in value. Assuming that they are the same, calculate the ratio of the reaction rate constants for these two reactions at 25 °C.

689
views
Textbook Question

Anthropologists can estimate the age of a bone or other sample of organic matter by its carbon-14 content. The carbon-14 in a living organism is constant until the organism dies, after which carbon- 14 decays with first-order kinetics and a half-life of 5730 years. Suppose a bone from an ancient human contains 19.5% of the C-14 found in living organisms. How old is the bone?

2725
views
Textbook Question

Consider the gas-phase reaction: H2(g) + I2(g) → 2 HI(g) The reaction was experimentally determined to be first order in H2 and first order in I2. Consider the proposed mechanisms. Proposed mechanism I: H2(g) + I2(g) → 2 HI(g) Single step Proposed mechanism II: I2(g) Δk1k-12 I(g) Fast H2( g) + 2 I( g) → k22 HI( g) Slow a. Show that both of the proposed mechanisms are valid.

650
views
Textbook Question

Consider the gas-phase reaction: H2(g) + I2(g) → 2 HI(g) The reaction was experimentally determined to be first order in H2 and first order in I2. Consider the proposed mechanisms. Proposed mechanism I: H2(g) + I2(g) → 2 HI(g) Single step Proposed mechanism II: I2(g) Δk1k-12 I(g) Fast H2( g) + 2 I( g) → k22 HI( g) Slow b. What kind of experimental evidence might lead you to favor mechanism II over mechanism I?

1631
views
Textbook Question

Consider the reaction: 2 NH3(aq) + OCl-(aq) → N2H4(aq) + H2O(l) + Cl- (aq) This three-step mechanism is proposed: NH3(aq) + OCl- (aq) Δk1k2 NH2Cl(aq) + OH- (aq) Fast NH2Cl(aq) + NH3(aq) →k3 N2H5+ (aq) + Cl- (aq) Slow N2H5+ (aq) + OH-(aq) →k4 N2H4(aq) + H2O(l) Fast a. Show that the mechanism sums to the overall reaction.

878
views