Chapter 5, Problem 66
Given the data N2(g) + O2(g) → 2 NO(g) ΔH = +180.7 kJ 2 NO(g) + O2(g) → 2 NO2(g) ΔH = -113.1 kJ 2 N2O(g) → 2 N2(g) + O2(g) ΔH = -163.2 kJ use Hess's law to calculate ΔH for the reaction N2O(g) + NO2(g) → 3 NO(g)
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Calculate the enthalpy change for the reaction P4O6(s) + 2 O2(g) → P4O10(s) given the following enthalpies of reaction: P4(s) + 3 O2(g) → P4O6(s) ΔH = -1640.1 kJ P4(s) + 5 O2(g) → P4O10(s) ΔH = -2940.1 kJ
From the enthalpies of reaction 2 C(s) + O2(g) → 2 CO(g) ΔH = -221.0 kJ 2 C(s) + O2(g) + 4 H2(g) → 2 CH3OH(g) ΔH = -402.4 kJ Calculate ΔH for the reaction CO(g) + 2 H2(g) → CH3OH(g)
From the enthalpies of reaction H2(g) + F2(g) → 2 HF(g) ΔH = -537 kJ C(s) + 2 F2(g) → CF4(g) ΔH = -680 kJ 2 C(s) + 2 H2(g) → C2H4(g) ΔH = +52.3 kJ Calculate H for the reaction of ethylene with F2: C2H4(g) + 6 F2(g) → 2 CF4(g) + 4 HF(g)
(c) What is meant by the term standard enthalpy of formation?
(a) Why does the standard enthalpy of formation of both the very reactive fluorine (F2) and the almost inert gas nitrogen (N2) both read zero?
For each of the following compounds, write a balanced thermochemical equation depicting the formation of one mole of the compound from its elements in their standard states and then look up H °f for each substance in Appendix C. (b) SO3(g)